Curriculum
Vitae: Thomas Junk
Department
of Chemistry 36
Magnolia Dr.
(318) 342-1830 junk@ulm.edu
http://www.ulm.edu/~junk/home.html
PROFESSIONAL
2004– Associate
Professor of Chemistry,
2001–2003 Assistant Professor of Chemistry, University
of Louisiana at Monroe and Adjunct Assistant Professor, Louisiana Tech
University.
1998–2000 Assistant Professor of
Chemistry,
1994–1997 Staff Research Scientist, Hazardous
1989–1993 Research Associate, Institute for Environmental
Studies,
RESEARCH
INTERESTS
Organic reactions under
non-classical (ultrasonicated, supercritical) conditions. Synthesis and application of stable isotope
labeled standards as environmental tracers.
Synthesis and characterization of organic compounds
containing heavy chalcogenides.
POSTDOCTORAL
EXPERIENCE
1989
EDUCATION
1983–88 Ph.D., Chemistry,
1983 B.S., Chemistry,
TEACHING
Spring ’98 CHEM 303-01, -02 (Organic I), CHEM 305-01
(Organic Lab 1)
Fall ’98 CHEM 303-01, -02 (Organic 1), CHEM 305-01
(Organic Lab 1)
Spring ‘99 CHEM 303-02 (Organic 1), CHEM 305-01, -03
(Organic Lab 1)
Fall ’99 CHEM 303-01, -02 (Organic I), CHEM 305-05
(Organic Lab 1)
Spring ’00 CHEM 303-02 (Organic 1), CHEM 305-03 (Organic
Lab 1), CHEM 532-01 (Spectral Identification of Organic Compounds, Graduate),
CHEM 109-01 (General Chemistry Lab)
Fall ’00 CHEM 304-01 (Organic 2), CHEM 306-01, -02
(Organic Lab 2), CHEM 110 (Qualitative Analysis)
Spring ’01 CHEM 305-03 (Organic Lab 1), CHEM 405-01
(Intermediate Organic Lab)
Fall ’01 CHEM 531-01 (Organic Synthesis,
Graduate), CHEM 303-03 (Organic 1), CHEM 301-03 (Seminar), CHEM 536-03
(Seminar, Graduate)
Spring ’02 CHEM 303-01 (Organic 1), CHEM 304-01 (Organic
2), CHEM 306-03, -05 (Organic Lab 2)
Fall ’02 CHEM 304-01 (Organic Lab 2), CHEM 405-01
(Intermediate Organic Lab)
Spring ‘03 CHEM 304-01 (Organic 2), CHEM 305-01 (Organic
Lab 1), CHEM 430-01 (Advanced Organic)
Fall ’03 CHEM 303-01 (Organic 1), CHEM 305-03, -05
(Organic Lab 1), CHEM 306-01 (Organic Lab 2)
Spring ’04 CHEM 304-01 (Organic 2), CHEM 305-03, -05
(Organic Lab 1), CHEM 405-01
(Intermediate Organic Lab)
Teaching Before Spring ’97:
1984 Teaching
Assistant, General Laboratories,
1996 Instructor,
Environmental Organic Chemistry 7003,
HONORS
1987 Departmental Graduate Research
Award,
1986 Robert A. Welch Predoctoral Research
Fellow.
SOCIETIES
Phi Lambda Upsilon, American
Chemical Society, Sigma Xi,
COLLEGE/UNIVERSITY COMMITTEE MEMBERSHIPS
1999-00
2001-02 Search
Committee for Dean of Pure and Applied Sciences at
2000-02
GRADUATE STUDENTS DIRECTED
Malinda L. Godwin, “Determination of Mercury Levels
in Crayfish by Cold Vapor Atomic Absorption Spectroscopy”, December 1999.
Sridevi Goskonda,
“Ultrasonic Treatment of Refractory Environmental Pollutants”, May 2000.
Rashmi Nair, “Synthesis and Characterization of
Novel Organotellurium Compounds”, Spring 2002.
Abdulrahman Alhazmi, “Halogen Exchange Reactions In
Superheated Aqueous Media”, Spring 2002.
Prabodhika R. Mallikaratchy,
“Synthesis of Novel Organotellurium Compounds”, Summer 2003.
UNDERGRADUATE STUDENTS DIRECTED
2001 Faculty Advisor, “Rapid Access to
Deuterium-Tagged Hydrocarbons and Their Functional Derivatives”, Student
Investigator: Aaron Clarke (funded by
the Petroleum Research Fund).
2001 Faculty Advisor, Howard Hughes project “Preparation
and Characterization of Propanil Degradation Products”. Student investigator: Brian Keator.
2001 Faculty Advisor, Howard Hughes project “Preparation
and Characterization of Nitroaromatic Compounds Related to
2,4,6-Trinitrotoluene (TNT)”. Student
investigator: Iveri Zhvania.
2001 Faculty Advisor, Howard Hughes project “Propanil
Degradation Products II: Preparation and
Characterization of Two Compounds Related to Tetrachlorazobenzene”. Student investigator: Brian Keator.
2001 ACS Project SEED
2002 Faculty Advisor, JBF Funded Project
“Chemical Reactions in Superheated Water”, Student Investigator: Adam Marchard.
2002-03 Faculty Advisor, Howard Hughes project “Propanil
Degradation Products III: Synthesis of
3-[2-Chloro-5-(3,4-dichlorophenylazo)-phenyl]-propanoic Acid, Preparation of
Polychlorinated Diaryl Amines”. Student
investigator: Matthew J. Sewell.
2003 ULM Emerging Scholars Program,
2003 Faculty Advisor, JBF Funded Project
“Chemical Reactions in Superheated Water”, Student Investigator: Kathrynn Pham.
2003 ACS Project SEED
2003 ULM
Emerging Scholars Program,
2004 Faculty
Advisor, student research project “Preparation of novel organotellurium
heterocycles”, Student investigator: Cathy Tran.
COMMUNITY SERVICE
2004– Director,
2003– Secretary,
2002 Chair,
2001 Acting
Chair and Chair-Elect,
1998–2000 Faculty Advisor, ACS Student Affiliates.
1995–1996 Sierra Club, Baton Rouge Group. Outings Chair and voting
member of the Executive Committee.
OTHER ACTIVITIES
Developer of commercial MS Windows based software
for GC and GC–MS file format conversions and data import/export routines. Programming languages: Pascal, C, C++, 0x86
Assembly.
CORPORATE, CONSULTING
1997 – pres. Consultant, development of a standardized
GC–MS file format interface (for the National Institute for Standards and
Technology, NIST).
1996 – pres. Consultant, GS–MS data processing automation
and software development (for ChemSW, Inc.).
1996 – 1998 Owner of JC Scientific, commercial MS Windows
based scientific software for export/format conversions of GC and GC–MS data
files.
PATENTS
T. Junk and W. J. Catallo “Process For Preparing
Deuterium–Tagged Compounds and Uses Therefore”, US. Patent
5,830,763, issued
W. J. Catallo and T. Junk “Transforming Biomass to Hydrocarbon
Mixtures in Near-Critical and Supercritical Water”, US. Patent
6,084,147, issued
SPONSORED RESEARCH
1993–1994 Sonochemical Treatment of Hazardous
Chlorinated Hydrocarbons in Water and Sediments, Gulf Coast Hazardous Substance
Research Center Grant, W. J. Catallo and T. Junk, $79,000.
1994–1995 Biodegradation of Toxic Chemicals from
Petroleum and Produced Waters in Brackish Marsh Sediments: Pathway Studies and Degradation Rate
Enhancement Using Deuterated Tracers,
1995–1996 Sonochemical
Treatment of Hazardous Organic Hydrocarbons:
Process Optimization and Pathway Studies,
1996–1997 Sonochemical Treatment of Hazardous Organic
Hydrocarbons II, Process Optimization and Pathway Studies, Project
Continuation, T. Junk and W. J. Catallo. $65,200.
1997-1998 Sonochemical Treatment of Hazardous Organic
Hydrocarbons III: Project Continuation,
June 1997–May 1998, $76,000.
1999 Departmental Enhancement: Acquisition of Core Equipment
for the Continuing Growth of the
1999-2000 Modernization of
1999-2000 Purchase of a Flammable Material Storage
Refrigerator for the Chemistry Department,
1999-2003 Rapid Access to Deuterium-Tagged
Hydrocarbons and Their Functional Derivatives via The Supercritical Deuterium Exchange
Technique, Petroleum Research Fund, T. Junk, $30,000.
2001 Chemical Structure Drawing Software,
2001-2002 Superheated Water as Environmentally
Friendly Reaction Medium, J. Bennett Johnston Science Foundation, T. Junk,
$5,000.
2002-2003 Upgrading
Pending: Fate and Environmental Impact of
Trinitrotoluene Transformation Products, T. Junk and W. J. Catallo,
LBRN-NIH, $91,000.
Total funding received to
date: $556,100.
JOURNAL PUBLICATIONS
1.
T. Junk and K. J. Irgolic, "4-Methoxyphenyltellurium
Trichloride”, Organomet. Synth. 1986,
3, 640–1.
2.
T. Junk and K. J. Irgolic, "2-Nitrophenyl(phenyl)
Selenide", Organomet. Synth. 1986,
4, 641–2.
3.
T. Junk and K. J. Irgolic, "Telluranthrene", Organomet. Synth. 1988,
4, 604-5.
4.
T. Junk and K. J. Irgolic, "Bis(3-chloro-2-pyridyl)
Ditelluride", Organomet. Synth. 1988,
4, 604–5.
5.
K. J. Irgolic, T. Junk, C. Kos, W. S. McShane, and G.
C. Pappalardo, "Preparation of Trimethyl-2-hydroxyethylarsonium
(Arsenocholine) Compounds", J. Appl. Organomet. Chem. 1987, 1,
403–12.
6. T. Junk and K. J. Irgolic, "Synthesis of
2-Methyl-3-azaareno[d]tellurophenes", Phosphorus
Sulfur 1988, 38, 121–35.
7.
G.Distefano, V.
Galasso, T. Junk, K. J. Irgolic and
G. C. Pappalardo, "Dipole Moments in the (I)-Photoelectron Spectroscopic
Studies of the Conformations of Thioselenanthrene, Thiotelluranthrene, and
Selenotelluranthrene",
Phosphorus Sulfur 1988, 38, 281–91.
8.
A. E. Meyers,
K. J. Irgolic, R. A. Zingaro, T. Junk,
R. Chakravorty, N. L. M. Dereu and K. French, "The Chrystal Structures of
9,10-Dichalcogenaanthracenes, C12H8(X,Y); (X,Y) = (S,
Se), (S, Te), (Se, Te) and (O, Se)", Phosphorus
Sulfur 1988, 2, 257–69.
9.
T. Junk and K. J. Irgolic, "5-Aza-10-tellura-5,10-dihydroanthracenes (Phenotellurazines)", Heterocycles 1989, 28, 1007–13.
10.
T. Junk, G. Gitzner, and K. J. Irgolic, "Improved
Preparation of Tetrahydroselenophene (Selenacyclopentane) and
Tetrahydrotellurophene (Telluracyclopentane) ", Synth. React. Inorg. Met.
Org. Chem. 1989, 19, 931–3.
11.
M. E. Amato, K. J. Irgolic, T. Junk, G. C. Pappalardo, and B. Perly, "H-1 and C-13 NMR
Spectra of rac-Bis(palmitoyloxy)-3-propyl-(2-trimethylarsinoethyl)
Phosphonate, an Arsenic–Containing Phosphonolipid", Mag. Res. in Chem. 1990,
28, 856–61.
12.
T. Junk and K. J. Irgolic, "Synthesis and
Characterization of rac-1,2-Bis(palmitoyloxy)-3-propyl-(2-trimethylarsinoethyl)
Phosphonate, an Arsenic–Containing Phosphonolipid", Appl. Organomet. Chem.
1990, 4(2), 103–9.
13.
T. Junk, K. J. Irgolic and E. A. Meyers, "Chrystal Structure
of Bis(3-chloro-2-pyridyl)
Ditelluride", Acta Cryst. 1992, C49, 975–6.
14.
T. Junk, K. J. Irgolic, J. H. Reibenspeis and E. A. Meyers,
"Structure of Phenotellurazine", Acta
Cryst., Section C:
Cryst. Struct. Commun. 1993, C49(5),
938–40.
15.
T. Junk, K. J. Irgolic and E. A. Meyers,
“Bis-(3-chloro-2-pyridyl) Ditelluride”, Acta
Cryst., Section C:
Cryst. Struct. Commun. 1993, C49(5),
975–6.
16. W. J.
Catallo and T. Junk, “Sonochemical
Dechlorination of Hazardous Wastes in Aqueous Systems”, Waste Management 1995, 15(4), 803–8.
17.
E. A. Meyers, T. Junk, and K. J. Irgolic, “Crystal
Structure of Trichloro(2-phenylselenophenyl)tellurium, TeSeCl3C12H9”, Z.
Kristallogr. 1995, 210, 552–3.
18.
T. Junk and W. J. Catallo, “Preparative Supercritical Deuterium
Exchange in Arenes and Heteroarenes”, Tetrahedron
Lett., 1996, 37, 3445–8.
19. T. Junk and F. R. Fronczek, “Photostimulated Telluromethylation”, Tetrahedron Lett., 1996, 37, 4361–2.
20. T. Junk, W. J. Catallo, L. D. Civils, “Synthesis of Polydeuterated Benzothiazoles via Supercritical Deuteration of
Anilines”, J. Labelled Compds. Radiopharm., 1997, 39(8), 625–30.
21.
T. Junk, W. J. Catallo, and J. Elguero. “Syntheses in Superheated
Aqueous Media: Preparation of Fully
Deuterated Pyrazoles and Quinoxalines”,
Tetrahedron Lett. 1997, 38(36), 6309–12.
22.
T. Junk and W. J. Catallo. “Hydrogen Exchange
Reactions Involving C–H (D, T) Bonds” (invited review paper), Chem. Soc. Rev. 1997, 26(5), 401–6.
23.
M. L. Jimeno,
24. T. Junk and W. J. Catallo, “Environmental Transformation Products of 2,4,6-Trinitrotoluene“, Chem.
Speciation Bioavail., 1998,
10(2), 47–52.
25. A. Muñoz, M. Sánchez, T.
Junk and A.Virgili, “The Preparation of Perdeuterio-2,2,2-trifluoro-1-(1-pyrenyl)ethanol: A Second Case of Chiral Recognition Between
Isotopomers”, J. Org. Chem. 2000, 65. 5069–71
26. E. F. Emery, T. Junk, R. E. Ferell and L. G. Butler,
“Solid State 2H MAS Studies of TNT Absorption in Soil and Clays”, Environ.
Sci. Technol. 2001, 35, 2973–8.
27. A. R.
Clark, R. Nair, F. R. Fronczek and T. Junk,
“Facile Access to Aryltellurium Compounds from Arylboronic Acids”, Tetrahedron
Lett.
2002, 43, 1387–9.
28.
S. Goskonda, W.
J. Catallo, and T. Junk,
“Sonochemical Degradation of Aromatic Organic Pollutants”, Waste Management
2002, 22(3), 351–6.
29. P. Mallikaratchy, R. E.
Norman, F. R. Fronczek and T. Junk, “Tribromo(3,5-dimethyl-2-nitrophenyl-κ2C1,O)tellurium(IV),
bromo(3,5-dimethyl-2-nitrophenyl- κ2C1,O)tellurium(II)
and bromo(3,5-dimethylnitrosophenyl- κ2C1,O)tellurium(II),
Acta Cryst. 2003, C59, o571–4.
30. W. J.
Catallo and T. Junk, “Effect of
Static vs. Tidal Hydrology on Pollutant Transformation in Wetland Sediments”, J.
Env.
Quality 2003, 32, 2421–7.
SUBMITTED
P. R. Mallikarachy, F. R.
Fronczek, H. O. Brotherton and T. Junk, “Facile Access to Novel
Organotellurium Heterocycles by Nitration of Bis-(3,5-Dimethylphenyl)
Ditelluride”, to be submitted to J. Heterocycl. Chem.
OTHER PUBLICATIONS
T. Junk and W. J. Catallo, “Sonochemical Treatment of Hazardous Organic
Hydrocarbons II: Process Optimization
and Pathway Studies”, Final Report to
the Gulf Coast Hazardous Substance Research Center, Lamar, TX, 1996.
W. J. Catallo and T. Junk, “Biodegradation of Toxic
Chemicals from Petroleum and Produced Water in Brackish Mash Sediments: Pathway Studies Using Deuterated Tracers”; Final Report,
T. Junk and W. J. Catallo, “Sonochemical Treatment of Hazardous Organic
Hydrocarbons II: Process Optimization
and Pathway Studies”, Final Report to the Gulf Coast Hazardous
Substance Research Center, Lamar, TX, 1996.
T. Junk and W. J. Catallo, “Sonochemical Treatment of Hazardous Organic
Hydrocarbons III:”,
Final Report to the Gulf Coast Hazardous
T. Junk, “Rapid Access to Deuterium
Tagged Hydrocarbons and Their Functional Derivatives via The Supercritical Deuterium Exchange Technique”, Year 1 Progess
Report, Petroleum Research Fund Annual Report 2000.
T. Junk, “Rapid Access to Deuterium
Tagged Hydrocarbons and Their Functional Derivatives via The Supercritical Deuterium Exchange Technique”, Year 2 Progess
Report, Petroleum Research Fund Annual Report 2001.
PRESENTATIONS
T. Junk (Presenter), "2-Methylareno[b]-3-azatellurophenes",
5th International Symposium on the Chemistry of Selenium and Tellurium
Chemists, Oakridge, TN, Aug. 24–28, 1987.
T. Junk (Presenter), "Thermal Extraction GC/MS for Determination of Trace
Pollutants", NATO Advanced Study Institute on Metal Speciation in the Environment",
T. R. Irvin, T. Junk and T. R. Sharp,
"Quantitation of Dieldrin and Aldrin in Soils and Tissues via Thermal Extraction GC/MS", Toxicologist 9(1), 1050, 28th Annual Meeting of
the Society of Toxicology, Feb. 27–
T. R. Irvin, T. Junk and E. B. Overton, “Thermal
Extraction GC/MS Analysis of Polycyclic Aromatic and Halogenated Hydrocarbons
in Tissues”, 502, 10th Annual
Meeting of the Society for Environmental Toxicology and Chemistry, Toronto,
Canada, Oct. 28–Nov. 2, 1989.
E. B. Overton, T. Junk (Presenter), C. B. Henry and T.
R. Irvin, "Application of Thermal Extraction GC/MS Analysis of Polycyclic
Aromatic Hydrocarbon Toxicants in Soils and Marine Sediments", P162,
10th Annual Meeting of the Society for Environmental Toxicology and
Chemistry, Toronto, Canada, Oct. 28–Nov. 2, 1989.
T. R. Irvin, T. Junk (Presenter), J. E. Martin, C.
B. Henry and E. B. Overton, "Thermal Chromatographic Isolation and
Identification of Tissue–Borne Hydrocarbon Toxicants", Toxicologist 10(1), 1345, 29th
Annual Meeting of the Society of Toxicology, Feb. 1990.
T. Junk, T. R. Irvin, K. C. Donnelly and D. J. Marek, “Evaluation of Thermal
Chromatographic Methods for the Rapid Measurement of Pesticides in Soils”, 367,
11th Annual Meeting of the Society for Environmental Toxicology and Chemistry,
T. R Irvin, P. R. Iyer, E.
K. Stevens, A. P. Zoeller and T. Junk,
"Coordinate Application of Mammalian Cell Culture Systems with GC/MS
Analysis for Toxicological Evaluation and Management of a Superfund Site”, to
Characterize Toxic Constituents in Complex Mixtures", P314, 12th Annual Meeting of the
Society for Environmental Toxicology and Chemistry, Seattle, Washington, Nov.
3–7, 1991.
T. Junk (Presenter) , T. R. Irvin, K. C. Donnelly and D. J. Marek,
“Quantification of Pesticides on Soils by Thermal Extraction–GC/MS”, 2nd
International Symposium of Field Screening Methods for Hazardous Wastes and
Toxic Chemicals, Las Vegas, Nevada, Feb. 12–14, 1991.
T. R. Irvin, T. Junk, E. K. Stevens and K. J.
Irgolic, “Prenatal Toxicity of Diphenyl Diselenide Evaluated by Rodent Embryo
Culture”, P333, 12th Annual Meeting of the Society for Environmental
Toxicology and Chemistry,
W. J. Catallo and T. Junk, “Pathway Transformation
Studies of Petroleum Hydrocarbons and Heterocycles in Marine Sediments Using
Deuterated Tracers”, International Oil Spill Conference; U.S. Coast
Guard/American Petroleum Institute/
T. Junk (Invited Presenter), “Heavy Chalcogenides in Organic Chemistry: Recent Advances in the Preparation of
Aryltellurium Compounds”,
T. Junk (Presenter and Session Chair) and K. J. Irgolic, “Recent Progress in
the Preparation of Aryltellurium Compounds”, 211th ACS National
Meeting,
T. Junk (Presenter) and W. J. Catallo, “Recent Progress in the Synthesis and
Characterization of 2,4,6-Trinitrotoluene (TNT)
Transformation Products, 211th ACS National Meeting,
W. J. Catallo and T. Junk, “Effect of Hydrology and
Associated Redox Conditions on Chemical Transformations in Wetland Sediments”,
HSRC South/Southwest Semiannual Conference, Baton Rouge, LA, Oct. 27–Oct. 29, 1996.
T. Junk (Presenter), W. J. Catallo, and L. D. Civils, “Environmental
Transformation Products of TNT – Analytical and Computational Studies”, HSRC South/Southwest
Semiannual Conference, Baton Rouge, LA, Oct. 27–Oct. 29, 1996.
S. J. Patel, Z. Lin, V. Van
Fleet–Stalder, T. Junk, and T. G.
Chasteen, “Toxicity of Novel Organotellurium Compounds Using Bacterial Growth
Inhibition”, Annual Meeting, Texas Academy of Science, Huntsvillle, TX, Mar.
6–8, 1997.
T. Junk (Invited Presenter), “Reactions Under Non–Classical Conditions”,
Kennesaw State University, GA,
T. Junk (Presenter) and W. J. Catallo, “The Properties and Environmental Fates
of 3,4-Dichloropropionanilide (Propanil) Degradation Products, 214th
ACS National Meeting, Las Vegas, Nevada, Sep. 7–11, 1997.
T. Junk (Presenter) and W. J. Catallo, “Sonochemical Treatment of Hazardous
Organic Hydrocarbons, an Emerging Remediation Technology”,
T. Junk (Presenter) and W. J. Catallo, “Sonochemical Remediation of Organic
Pollutants”, 216th ACS National Meeting,
E. F. Emery, T. Junk,
and L. G. Butler, “Solid State Deuterium MAS NMR Studies of TNT/Soil
Adsorption”, 54th ACS Southwest Regional Meeting, Baton Rouge, LA,
Nov. 1 – Nov. 3, 1998.
W. J. Catallo and T. Junk, “Transformation of Organic
Chemicals in High Energy Aqueous Systems”, Federation of Analytical Chemists
South and Southwest Meeting (ACSSM),
S. Goskonda, T. Junk, and W. J. Catallo, “Ultrasonic
Treatment of Refractory Environmental Pollutants”,
E. F. Emery, L. G. Butler, T. Junk, R. Ferrel, “Solid-State
Deuterium MAS NMR Studies of TNT/Soil
Adsorption”, 218th ACS National Meeting, New Orleans, LA, Aug.
22–26, 1999.
M. L. Godwin, H. O.
Brotherton, and T. Junk, “Mercury Levels in Crayfish”, Louisiana
Academy of Sciences Annual Meeting, Shreveport, Louisiana, February 4, 2000.
A. Alhazmi and T. Junk,
“Organic Syntheses in Superheated Water”,
R. Nair and T. Junk,
“Advances in the Preparation and Characterization of Organotellurium
Compounds”, Louisiana Academy of Sciences Annual Meeting, Monroe, Louisiana,
February 2, 2001.
R. Nair and T. Junk
(Presenter), “Organotellurium Compounds with Strong Intramolecular Te-N or Te-O
Coordination”, 222nd ACS National Meeting,
A. J. Marchand, A. Alhazmi
and T. Junk (Presenter), “Superheated Water as Environmentally Friendly
Reaction Medium”, Environmental State of the State (ESOS) Conference VII,
R. Tsai and T. Junk,
“Chemical Reactions in Superheated Aqueous Media”,